Table 2. 1H- and 13C-NMR data of 9, 10, and 13 in CD3OD

Position 9 10 13
δH (Int., Multi., J in Hz) δC δH (Int., Multi., J in Hz) δC δH (Int., Multi., J in Hz) δC
1 - 131.25 - 129.51 - 131.28
2 7.24 (1H, d, 2.0) 114.67 7.25 (1H, d, 2.4) 112.71 7.09 (1H, d, 1.8) 112.43
3 - 150.26 - 147.01 - 151.12
4 - 148.43 - 146.45 - 149.64
5 6.93 (1H, d, 8.0) 117.11 6.58 (1H d, 9.6) 114.32 7.07 (1H, d, 8.4) 117.68
6 6.85 (1H, dd, 8.0, 2.0) 124.35 6.86 (1H, dd, 9.6, 2.4) 122.37 7.02 (1H, dd, 8.4, 1.8) 122.84
7 6.53 (1H, d, 12.5) 137.71 6.53 (1H, d, 14.4) 135.70 7.36 (1H, d, 15.6) 141.48
8 5.79 (1H, d, 12.5) 123.41 5.80 (1H, d, 14.4) 121.33 6.39 (1H, d, 15.6) 120.61
9 - 170.14 - 168.16 - 168.94
3-OCH3 3.71 (3H, s) 56.78 3.71 (3H, s) 57.44 3.80 (3H, s) 56.83
1' - 131.55 - 130.03 - 131.39
2' 6.57 (1H, d, 8.5) 116.37 6.66 (1H, d, 1.8) 116.49 6.62 (1H, d, 8.7) 116.40
3' 6.87 (1H, d, 8.5) 130.84 - 144.12 6.96 (1H, d, 8.7) 130.88
4' - 157.03 - 148.25 - 157.11
5' 6.87 (1H, d, 8.5) 130.84 6.96 (1H, d, 9.6) 115.08 6.96 (1H, d, 8.7) 130.88
6' 6.57(1H, d, 8.5) 116.37 6.49 (1H, dd, 9.6, 1.8) 120.34 6.62 (1H, d, 8.7) 116.40
7' 2.57 (2H, t, 7.0) 35.65 2.59 (2H, t, 9.0) 34.10 2.66 (2H, t, 7.8) 35.92
8' 3.40 (2H, t, 7.0) 42.44 3.38 (2H, t, 9.0) 40.41 3.37 (2H, t, 7.8) 42.71
3'-OCH3 - - 3.67 (3H, s) 54.45 - -
1'' 4.82 (1H, d, 7.5) 102.45 4.83 (1H, d, 8.4) 100.42 4.95 (1H, d, 7.8) 102.44
2'' 3.26-3.75 (6H, m) 74.95 3.25-3.75 (6H, m) 72.96 3.30-3.78 (6H, m) 74.97
3'' 77.92 75.93 78.01
4'' 71.38 69.40 71.43
5'' 78.31 76.30 78.43
6'' 62.56 60.59 62.61