Table 1. Accuracy, precision, correlation coefficient, limit of detection (LOD), and limit of quantification (LOQ) of mineral and hazardous heavy metal analysis by atomic absorption spectrophotometer (AAS) and inductively coupled plasma mass spectrometer (ICP/MS)
Instrument | Mineral | Accuracy (%) | Precision (RSD%) | Correlation coefficient (R2) | LOD (mg/kg) | LOQ (mg/kg) |
AAS | Na | 97.40 | 0.03 | 0.9954 | 0.1945 | 0.5894 |
Mg | 95.40 | 0.01 | 0.9984 | 0.1586 | 0.4807 |
K | 109.40 | 0.02 | 1.0000 | 0.2394 | 0.7255 |
Ca | 94.60 | 0.03 | 0.9990 | 0.7920 | 2.4000 |
ICP/MS | Cr | 98.46 | 2.30 | 0.9999 | 0.0098 | 0.0296 |
Cu | 98.34 | 1.40 | 1.0000 | 0.0090 | 0.0274 |
Cd* | 101.20 | 2.00 | 1.0000 | 0.0004 | 0.0014 |
Pb* | 99.90 | 0.60 | 0.9993 | 0.5000 | 1.6000 |
The unit of LOD and LOQ is μg/kg.